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H_3PO_4 solution hydrothermal carbonization combined with KOH activation to prepare argy wormwood-based porous carbon for high-performance supercapacitors

机译:H_3PO_4溶液水热碳化与KOH活化相结合制备用于高性能超级电容器的基于艾草艾草的多孔碳

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摘要

In this work, argy wormwood-based porous carbon electrode materials for high-performance supercapacitors are prepared through H3PO4 solution hydrothermal carbonization and subsequent KOH activation. The obtained carbon has a specific surface area (SSA) of 927 m(2) g(-1), a total pore volume of 0.56 cm(3) g(-1), and a high oxygen (9.38%) content. In three-electrode system, it exhibits specific capacitance of 344 F g(-1) at 1 A g(-1). Moreover, the symmetric supercapacitor shows an excellent rate capability of 87% retention from 1 A g(-1) to 10 A g(-1), and a good cycling performance with 91.6% retention over 5000 cycles in 6 M KOH. Therefore, the sample activated by H3PO4 & KOH exhibits an excellent future in energy storage. (C) 2018 Elsevier B.V. All rights reserved.
机译:在这项工作中,通过H3PO4溶液的水热碳化和随后的KOH活化,制备了用于高性能超级电容器的基于艾草的多孔碳电极材料。获得的碳的比表面积(SSA)为927 m(2)g(-1),总孔体积为0.56 cm(3)g(-1),并且氧含量较高(9.38%)。在三电极系统中,它在1 A g(-1)时表现出344 F g(-1)的比电容。此外,对称超级电容器在1 M g(-1)至10 A g(-1)中显示出极好的速率能力,保留率达87%,在6 M KOH中的5000次循环中具有91.6%的保留率。因此,被H3PO4和KOH活化的样品在储能方面显示出了极好的前景。 (C)2018 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2018年第30期|105-117|共13页
  • 作者单位

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

    Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Porous carbon; Argy wormwood; Hydrothermal carbonization; Activation; Supercapacitor;

    机译:多孔碳;艾草;热碳化;活化;超级电容器;

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