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Aqueous solution-processed MoO_3 thick films as hole injection and short-circuit barrier layer in large-area organic light-emitting devices

机译:水溶液处理的MoO_3厚膜作为大面积有机发光器件中的空穴注入和短路阻挡层

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摘要

Thick molybdenum trioxide (MoO_3) films (ca. 120nm) were successfully deposited by an aqueous solution-processed method based on direct dissolution of the powder of ammonium molybdate ((NH_4)_6Mo_7O_(24)·4H_2O) precursors in deionized water. X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS) analyses showed that aqueous solution-processed MoO_3 (SMoO_3) has almost the same characteristics as the vacuum-evaporated MoO_3 (eMoO_3). Besides acting as a hole injection material, thicker MoO_3 operated as a short-circuit barrier layer in large-scale organic light-emitting devices (OLEDs). The successful fabrication of 150 × 150 mm~2 lighting panels confirmed the dual function of thick sMoO_3 films in large-area OLEDs.
机译:基于将钼酸铵((NH_4)_6Mo_7O_(24)·4H_2O)前体直接溶解在去离子水中的水溶液处理方法,成功沉积了厚约三氧化钼(MoO_3)膜(约120nm)。 X射线光电子能谱(XPS)和紫外光电子能谱(UPS)分析表明,水溶液处理的MoO_3(SMoO_3)具有与真空蒸发的MoO_3(eMoO_3)几乎相同的特性。除了用作空穴注入材料外,更厚的MoO_3在大型有机发光器件(OLED)中还用作短路阻挡层。 150×150 mm〜2照明面板的成功制造证实了厚sMoO_3膜在大面积OLED中的双重功能。

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  • 来源
    《_Applied Physics Express》 |2014年第11期|111601.1-111601.4|共4页
  • 作者单位

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123, China;

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