Associations and dissociations with time-dependent reaction coefficients in finite polymer mixtures: The model and analytical-numerical method for solution by successive approximations

摘要

The work deals with the association and dissociation reactions with time-dependent coefficients in finite mixtures of polymers dispersed in fluid media with solid components. The polymers are regarded to be formed by identical units, polymer-forming units (PFUs) and, thus, present homopolymers. The model takes into account the porosity of the dispersion-medium/polymer-mixture system. The work derives the model for the reactions in the finite mixtures. The model presents a non-autonomous quadratic finite ODE system in a time-independent hyperplane and is based on the conservation law for the total number of PFUs. A variety of engineering applications of the derived finite-mixture model are discussed. The simplest case of the finite mixtures, i.e., the monomer-dimer mixtures with time-independent reaction coefficients is completely analyzed. An analytical-numerical (AN) method of the successive-approximations (SA) type is proposed for solving the derived model. The AN/SA method includes explicit analytical expressions for each of the approximations in terms of the preceding approximation. The method is exact in the dissociation-only case. The approximations are expected to converge if the association-reaction coefficients are not too large and the zeroth approximations are not very far from the solution. The AN/SA method comprises two sequences of the approximations. If the first one converges uniformly in the entire time axis, then the limit function is a steady-state (or “dynamic equilibrium”) solution of the non-autonomous quadratic ODE system. The second sequence presumes that the first sequence is convergent in the above mentioned sense. The second sequence is intended for calculation of the solutions of initial-value problems for the above ODE system in a semi-infinite time interval. The main differences from common computational methods are formulated. The AN/SA method is quantitatively illustrated with a few examples of the settings in the aforementioned case of monomer-dimer mixtures, also in comparison with the explicit Euler method. The form of the AN/SA method allows especially efficient implementation on multi-processor/multi-core personal computers with graphic processing units even if the dimension of the state space is large. The developed model and method form a constructive framework for analysis or design of polymer mixtures dispersed in fluid-solid media. An application to prospective manufacturing of spatially heterogeneous polymer products is noted. A few directions for future research are proposed as well.