Titanocene(III) Chloride-Mediated Reductions of Oxazines Hydroxamic Acids and N-Hydroxy Carbamates

摘要

Titanocene (III) chloride (Cp2TiCl), generated in situ, reduces N-O bonds of various substrates in good to excellent yields (72–95%). Reactions may be performed with stoichiometric Cp2TiCl or with catalytic Cp2TiCl.