Synthesis and characterization of multiwalled CNT–PAN based composite carbon nanofibers via electrospinning

摘要

Electrospun fibrous membranes find place in diverse applications like sensors, filters, fuel cell membranes, scaffolds for tissue engineering, organic electronics etc. The objectives of present work are to electrospun polyacrylonitrile (PAN) nanofibers and PAN–CNT nanocomposite nanofibers and convert into carbon nanofiber and carbon-CNT composite nanofiber. The work was divided into two parts, development of nanofibers and composite nanofiber. The PAN nanofibers were produced from 9 wt% PAN solution by electrospinning technique. In another case PAN–CNT composite nanofibers were developed from different concentrations of MWCNTs (1–3 wt%) in 9 wt% PAN solution by electrospinning. Both types of nanofibers were undergone through oxidation, stabilization, carbonization and graphitization. At each stage of processing of carbon and carbon-CNT composite nanofibers were characterized by SEM, AFM, TGA and XRD. It was observed that diameter of nanofiber varies with processing parameters such as applied voltage tip to collector distance, flow rate of solution and polymer concentrations etc. while in case of PAN–CNT composite nanofiber diameter decreases with increasing concentration of CNT in PAN solution. Also with stabilization, carbonization and graphitization diameter of nanofiber decreases. SEM images shows that the minimum fiber diameter in case of 3 wt% of CNT solution because as viscosity increases it reduces the phase separation of PAN and solvent and as a consequence increases in the fiber diameter. AFM images shows that surface of film is irregular which give idea about mat type orientation of fibers. XRD results show that degree of graphitization increases on increasing CNT concentration because of additional stresses exerting on the nanofiber surface in the immediate vicinity of CNTs. TGA results shows wt loss decreases as CNT concentration increases in fibers.