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Ni-Mo / Synthesis method of Silicon/Carbon nanofibers composites based on Ni and Mo catalysts and manufacturing method of Lithium Secondary Batteries with anode materials of it

机译:Ni-Mo /基于Ni和Mo催化剂的硅/碳纳米纤维复合材料的合成方法以及使用其负极材料的锂二次电池的制造方法

摘要

(A) mixing nickel nitrate and ammonium molybdate in a molar ratio of any one of 10: 0, 8: 2, 6: 4, 5: 5, 4: 6, 2: 8, And dissolving in distilled water together with the support; (b) dropping the solution of precipitant dissolved in the dissolved solution and distilled water together with another distilled water, mixing and stirring; (c) filtering the stirred solution and drying the precipitate to form a Ni-Mo binary metal catalyst powder; (d) mixing the silicon and the bimetallic catalyst catalyst in a weight ratio of 8: 2, 6: 4, 5: 5, 4: 6 and 2: 8 to form a dispersion solution, ; And (e) synthesizing a composite material of silicon / carbon nanofibers by using chemical vapor deposition on the composite powder. As described above, the present invention provides a carbon nanotube having uniformly grown carbon nanofibers, a high average value of carbon elements, a low amorphousness, an excellent crystallinity and a very high specific surface area, Provided is a method for producing a composite fiber material, and a method for manufacturing a secondary battery having a high charge / discharge capacity efficiency by using the method.
机译:(A)以10:0、8:2、6:4、5:5、4:6:2、8中的任一种的摩尔比混合硝酸镍和钼酸铵,并将其与载体一起溶解在蒸馏水中; (b)将溶解在沉淀剂中的沉淀剂溶液和蒸馏水与另一种蒸馏水一起滴加,混合并搅拌; (c)过滤搅拌的溶液并干燥沉淀物以形成Ni-Mo二元金属催化剂粉末; (d)以8:2、6:4、5:5、4:6和2:8的重量比混合硅和双金属催化剂,以形成分散液;并且(e)通过在复合粉末上使用化学气相沉积来合成硅/碳纳米纤维的复合材料。如上所述,本发明提供了具有均匀生长的碳纳米纤维,高的碳元素平均值,低的非晶性,优异的结晶度和非常高的比表面积的碳纳米管,提供了一种复合纤维材料的制造方法。以及通过使用该方法制造具有高充电/放电容量效率的二次电池的方法。

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