111-Trifluoro-4-(thio­phen-2-yl)-4-(2-{444-trifluoro-3-oxo-1-(thio­phen-2-yl)but-1-en-1-ylamino}­eth­yl)amino­but-3-en-2-one

摘要

The asymmetric unit of the diamine compound, C18H14F3N2O2S2, consists of two mol­ecules; the C=C double bond has a Z configuration in the C4H3S—C=C—C(=O)—C segment. The –NH—CH2—CH2—NH chain adopts a twisted U-shape. The amino group is an intra­molecular hydrogen-bond donor to the carbonyl group; the intra­molecular hydrogen bond generates a six-membered ring. In both mol­ecules, the thienyl rings are disordered over two positions; the occupancies of the major components are 0.817 (4) and 0.778 (4) in one mol­ecule and 0.960 (4) and 0.665 (4) in the other. One of the trifluoro­methyl groups is disordered over two positions with the major component having 0.637 (8) occupancy.