Development of an Ultra-Pure Carrier-Free 209Po Solution Standard

摘要

Ultra-pure, carrier-free ²⁰⁹Po solution standards have been prepared and standardized for their massic alpha-particle emission rate. The standards, which will be disseminated by the National Institute of Standards and Technology (NIST) as Standard Reference Material SRM 4326a, have a mean mass of (5.169 ± 0.003) g of a solution of polonium in nominal 2.0 mol▪L⁻¹ HCl (having a solution density of (1.032 ± 0.002) g▪ mL⁻¹ at 20 °C) that are contained in 5 mL, flame-sealed, borosilicate glass ampoules. They are certified to contain a ²⁰⁹Po massic alpha-particle emission rate of (39.01 ± 0.18) s⁻¹▪g⁻¹ as of a reference time of 1200 EST, 01 December 2013. This new standard series replaces SRM 4326 that was issued by NIST in 1994. The standardization was based on 4πα liquid scintillation (LS) spectrometry with two different LS counting systems and under wide variations in measurement and counting source conditions. The methodology for the standardization, with corrections for detection of the low-energy conversion electrons from the delayed 2 keV isomeric state in ²⁰⁵Pb and for the radiations accompanying the small 0.45 % electron-capture branch to ²⁰⁹Bi, involves a unique spectral analysis procedure that is specific for the case of ²⁰⁹Po decay. The entire measurement protocol is similar, but revised and improved from that used for SRM 4326. Spectroscopic impurity analyses revealed that no photon-emitting or alpha-emitting radionuclidic impurities were detected. The most common impurity associated with ²⁰⁹Po is ²⁰⁸Po and the activity ratio of ²⁰⁸Po/²⁰⁹Po was < 10⁻⁷.