A Linear-Quadratic Model for the Quantification of a Mixture of Two Diluted Gases with a Single Metal Oxide Sensor

摘要

The aim of our work is to quantify two gases (acetone and ethanol) diluted in an air buffer using only a single metal oxide (MOX) sensor. We took advantage of the low selectivity of the MOX sensor, exploiting a dual-temperature mode. Working at two temperatures of the MOX sensitive layer allowed us to obtain diversity in the measures. Two virtual sensors were created to characterize our gas mixture. We presented a linear-quadratic mixture sensing model which was closer to the experimental data. To validate this model and the experimental protocol, we inverted the system of quadratic equations to quantify a mixture of the two gases. The linear-quadratic model was compared to the bilinear model proposed in the literature. We presented an experimental evaluation on mixtures made of a few ppm of acetone and ethanol, and we obtained a precision close to the ppm. This is an important step towards medical applications, particularly in terms of diabetes, to deliver a non-invasive measure with a low-cost device.