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Dynamics of Systems with Large Number of Degrees of Freedom and Generalized Transformation Theory

机译:大自由度系统的动力学和广义变换理论

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摘要

A generalized transformation theory which leads to a non-Hamiltonian description of dynamics is introduced. The transformation is such that all averages of observables remain invariant. However, the time evolution of the density matrix can no longer be expressed in terms of a commutator with the Hamiltonian. Therefore such transformations are not canonical in the usual sense. An explicit „two components” representation of the equations of motion is given which has the following properties: (a) each of the components satisfies a separate equation of motion, and (b) one component satisfies a kinetic equation of a generalized Boltzmann type.We obtain, therefore, the most remarkable result that the relation between dynamics and statistical mechanics (or thermodynamics) takes a specially transparent and simple form: thermodynamics appears in a precise sense as the random phase approximation of dynamics.Other problems such as the meaning of diagonalization of the Hamiltonian and definition of excitations will be treated in a forthcoming paper.
机译:引入了导致非哈密尔顿动力学描述的广义变换理论。这样的转换使得所有可观测值的平均值保持不变。但是,密度矩阵的时间演化不再可以用哈密顿量的换向器表示。因此,这种转换在通常意义上不是规范的。给出了运动方程的明确的“两个分量”表示,它具有以下特性:(a)每个分量满足一个单独的运动方程,并且(b)一个分量满足广义Boltzmann类型的动力学方程。因此,我们得到的最引人注目的结果是,动力学与统计力学(或热力学)之间的关系采取了一种特别透明和简单的形式:热力学在精确意义上表现为动力学的随机相位近似。哈密​​顿量的对角线化和激发的定义将在即将发表的论文中讨论。

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