Sources and Characteristics of Polycyclic Aromatic Hydrocarbons in Ambient Total Suspended Particles in Ulaanbaatar City Mongolia

摘要

The purpose of this study was to identify pollution sources by characterizing polycyclic aromatic hydrocarbons from total suspended particles in Ulaanbaatar City. Fifteen polycyclic aromatic hydrocarbons were measured in total suspended particle samples collected from different sites, such as the urban center, industrial district and ger (Mongolian traditional house) areas, and residential areas both in heating (January, March), and non-heating (September) periods in 2017. Polycyclic aromatic hydrocarbon concentration ranged between 131 and 773 ng·m⁻³ in winter, 22.2 and 530.6 ng·m⁻³ in spring, and between 1.4 and 54.6 ng·m⁻³ in autumn. Concentrations of specific polycyclic aromatic hydrocarbons such as phenanthrene were higher in the ger area in winter and spring seasons, and the pyrene concentration was dominant in late summer in the residential area. Polycyclic aromatic hydrocarbons concentrations in the ger area were particularly higher than the other sites, especially in winter. Polycyclic aromatic hydrocarbon ratios indicated that vehicle emissions were likely the main source at the city center in the winter time. Mixed contributions from biomass, coal, and petroleum combustion were responsible for the particulate polycyclic aromatic hydrocarbon pollution at other sampling sites during the whole observation period. The lifetime inhalation cancer risk values in the ger area due to winter pollution were estimated to be 1.2 × 10⁻⁵ and 2.1 × 10⁻⁵ for child and adult exposures, respectively, which significantly exceed Environmental Protection Agency guidelines.