均相催化O2氧化醇的研究进展（上）

摘要

综述了以分子氧为氧源的催化氧化醇体系，包括过渡金属（Cu，Fe，Co，V，Ru，Pd，Au）催化体系、非金属催化体系（2，2，6，6-四甲基哌啶氮氧自由基）及2，3-二氯-5，6-二氰对苯醌等其他小分子体系。对各催化体系的适用范围和优缺点进行了分析，阐述了主要催化体系的催化机理，对已有研究成果进行了总结，并在此基础上对该领域的发展趋势作了展望。%Advances in the selective alcohol oxidation with molecular oxygen catalyzed by homogeneous catalyst systems,namely homogeneous transition metal(Cu,Fe,Co,V,Ru,Pd, Au) catalytic systems,non-metal catalytic system(2,2,6,6-tetramethyl-piperidyl-1-oxy) and small organic molecule catalytic systems(2,3-dichloro-5,6-dicyano-1,4-benzoquinone),to aldehydes or ketones were reviewed. The application,advantages and disadvantages of the catalytic systems were discussed. The possible catalytic mechanisms of the main catalytic systems were focused on. Based on the existing researches,the development trends in this fi eld were also forecasted.