联邻甲苯胺缩PMBP及其配合物的合成

摘要

Two novel Schiff bases, tolidine-PMBP(L') and tolidine-bisPMBP( L) , were synthesized from ortho-tolidine and 1-phenyl-3-methyl-4-benzoyl-pyrazolone ( PMBP) by solid method. Three complexes of L with Co( II ) , Cu( II ) or Ni( II ) were prepared. The structures were characterized by UV, 1H NMR, IR and elemental analysis.%以联邻甲苯胺和1-苯基-3-甲基-4-苯甲酰基吡唑啉酮(PMBP)为原料,采用固相法合成了两种新型Schiff碱——联邻甲苯胺单缩PMBP(L′)和联邻甲苯胺双缩PMBP(L)；L分别与Cu(Ⅱ),Ni(Ⅱ)和Co(Ⅱ)配合制得三个对应的Schiff碱配合物,其结构经UV,1H NMR,IR和元素分析表征.