Binuclear Copper (Ⅰ) Complex {Cu[μS2P(C2H5O)2](C10H8N2)}2 was synthesized and characterized by elemental analysis, IR and X-ray diffraction analysis. The crystal belongs to triclinic system, space group P1 with Z=1,cell dimentions are a=1.0613(5),b=1.0723(3),c= 0.9397 (2)nm,α=111.11(4),β=115.57(6), γ= 85.28(2)°, V=0.8583(6)nm3.The structure was refined to R=0.039 and Rw=0.042 for 2527 reflection with I≥3σ(I). The complex exists as a centrosymmetric dimer with a Cu-S-P-S-Cu-S-P-S chair ight-membered ring in which Cu atoms are bridged by di-μ-S-P-S groups.
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