首页> 中文期刊> 《中国粉体技术》 >化学镀制备Pd催化剂及在甲醛催化燃烧中的应用

化学镀制备Pd催化剂及在甲醛催化燃烧中的应用

         

摘要

为实现采用催化燃烧法对甲醛进行净化处理,采用化学镀法制备Pd-堇青石蜂窝陶瓷整体式催化剂,并对催化剂进行表征和活性评价.结果表明:化学镀法可以实现纳米Pd微晶颗粒在堇青石蜂窝陶瓷载体上均匀负载,焙烧后PdO与载体结合牢固,具有良好的抗振荡性和热稳定性;500℃焙烧的Pd-堇青石蜂窝陶瓷整体式催化剂的催化活性最高,在甲醛质量浓度为0.4~10 mg/m3,空速为1 500~6 000 h-1的条件下,催化剂具有良好的活性.%The catalytic combustion method was used for the purification of formaldehyde. Pd-cordierite monolithic catalysts were prepared by electroless plating method. The catalyst was characterized and had active evaluation. The results showed that Pd nano-particles were obtained and dispersed symmetrically over cordierite substrates without the coating. PdO had a strong adhlhesion to the substrate and it had a good anti-vibration and thermostability after calcined. Pd-cordierite monolithic catalysts had the highest activity calcined at 5001, the catalysts had a good catalytic activity in large rage of formaldehyde mass concentration of 0.4~10 g/m3 and space velocity of 1500~6 000 h-1.

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