制备方法对Li_（1.2）Ni_（0.17）Co_（0.07）Mn_（0.56）O_2富锂正极材料电化学性能的影响

摘要

Lithium rich Li1.2Ni0.17Co0.07Mn0.56O2 cathode materials for lithium ion batteries were synthesized by three different methods:a spray-drying method,a co-precipitation method and a solid-state reaction method.Electrochemical tests show that the sample prepared by the spray-drying method presents the best cycling performance with discharge capacity of 153.4 mA?h?g-1 at 1 C rate.No degradation was observed after 50 cycles.While the samples prepared by the co-precipitation method and the solid-state reaction method delivered the capacity of 133.5 mA?h?g-1 and 123.6 mA?h? g-1,respectively,after 50 cycles under 1 C rate charge-discharge.The results of ICP measurements indicate that only the composition of the sample prepared by the spray-drying method can exactly consist with the formula Li1.2Ni0.17Co0.07Mn0.56O2.Furthermore,FSEM observation shows that the sample by spray-drying method has smaller particle size with even particle size distribution,which would benefit its electrochemical performance.%采用喷雾干燥法、共沉淀法、固相法3种方法制备化学计量式为Li1.2Ni0.17Co0.07Mn0.56O2的锂离子电池富锂正极材料。电化学测试表明,喷雾干燥法制备的材料电化学性能最好,0.1 C充放电首圈脱锂和嵌锂容量分别为283.9 mA/（h g）和231.7 mA/（h g）。与共沉淀法和固相法相比较,喷雾干燥法制备的材料1 C倍率充放电时表现出良好的循环稳定性,50次循环后容量没有衰减,仍为153.4 mA/（h g）,共沉淀法和固相法制备的材料50次循环放电容量分别为133.5 mA/（h g）和123.6 mA/（h g）。ICP分析结果指出,喷雾干燥法制备的电极材料元素比例最符合初始的Li1.2Ni0.17Co0.07Mn0.56O2设计配比。而且喷雾干燥法制备的材料颗粒更为细小均匀,有利于提高材料的电化学性能。