一维聚硫杂酞菁铁对Li/SOCl2电池的催化作用

摘要

Catalysis of 1-D polymers of iron thiaphthalocyanine [P(FePcS2)] to the lithium/thionyl chloride (Li/SOCl2) cell was studied by adding different content of catalyst into electrolyte. When discharged with the current density of 15 Ma/cm2 at 25 °C, 55 °C and - 40 °C , the voltage of cell with P( FePcS2) content of 1.0 g/L increased about 120 Mv, 122 Mv and 230 Mv, respectively, the capacity increased about 1.30 Ah,0.60 Ah and 0.55 Ah,respectively.%在电解液中加入不同含量的催化剂,研究了一维聚硫杂酞菁铁[ P( FePcS2)]对锂/亚硫酰氯(Li/SOCl2)电池的催化作用.P(FePcS2)含量为1.0 g/L的电池以15 mA/cm2的电流密度放电,在25 ℃、55℃及- 40℃时的电压分别提高约120mV、122 mV和230 mV,容量分别提高约1.30 Ah、0.60 Ah和0.55 Ah.