The research progress on catalyst of esterification of carboxylic acid and olefin was reviewed since 1960s. The catalysts include sulfonic acid,polyphosphoric acid,ionic liquid,silicate catalysts,zeolite , ion exchange resin, heterpolyacid. Their catalytic reactivities were compared. The research directions of catalysts to be used in esterification of carboxylic acid and olefin in the future were also proposed.%综述了20世纪60年代以来羧酸和烯烃酯化合成羧酸酯反应中催化剂的研究进展,包括磺酸类催化剂、多磷酸、离子液体、硅酸盐类催化剂、沸石分子筛催化剂、离子交换树脂、杂多酸类催化剂等,比较了各类催化剂的催化活性,并展望了羧酸和烯烃酯化反应的催化剂研究方向.
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