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Intermediate band solar cells based on indium arsenide quantum dots embedded in indium gallium arsenide quantum well.

机译:基于砷化铟镓量子阱中嵌入的砷化铟量子点的中带太阳能电池。

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摘要

Intermediate band solar cells based on quantum dots and quantum wells with anti-reflection coating are investigated in this thesis. The demand for high efficient solar cells as an alternate source of energy is the main motivation for this research project. Intermediate band solar cells based on quantum dots were the subject of intensive research in recent years. High power conversion efficiency was predicted from InAs/GaAs intermediate band solar cells as the presence of InAs quantum dots increased the absorption below the band gap of the host material.;In this thesis, an attempt has been made to further increase the absorption of GaAs solar cells by embedding InAs quantum dots in InxGa 1-xAs quantum wells. The quantum efficiency and spectral response measurements of quantum dots embedded in quantum well devices exhibit an extended response till 1280 nm in the near infrared region of the electromagnetic spectrum. The interband transition peaks associated with the InxGa 1-xAs quantum well exhibit a red shift as In mole fraction (x) in In xGa1-xAs quantum well is increased above 0%. The short circuit current density increased, while open circuit voltage decreased, as x is increased.;In addition, the use of inexpensive anti-reflection coating (ARC) on these intermediate band solar cells has been studied. Anti-reflection coating based on Zinc oxide (ZnO) has significantly improved the power conversion efficiency of the solar cells. The ZnO synthesized using sol-gel technique was spin coated on the solar cells and subsequently annealed. The short circuit current density was significantly increased after the deposition of the ARC. Enhancement of the order of 42 % in the power conversion efficiency was obtained. Around 43% enhancement in quantum efficiency and 44% enhancement in spectral response measurements were also observed.
机译:本文研究了基于量子点和量子阱的抗反射涂层中频太阳能电池。对高效太阳能电池作为替代能源的需求是该研究项目的主要动力。近年来,基于量子点的中频太阳能电池已成为研究的热点。从InAs / GaAs中间带太阳能电池中可以预测到高功率转换效率,因为InAs量子点的存在会增加吸收率,使其低于基质材料的带隙。;本文试图进一步提高GaAs的吸收率通过将InAs量子点嵌入InxGa 1-xAs量子阱中来形成太阳能电池。嵌入量子阱设备中的量子点的量子效率和光谱响应测量在电磁光谱的近红外区域中显示出扩展的响应,直至1280 nm。当In xGa1-xAs量子阱中的In摩尔分数(x)增加到0%以上时,与InxGa 1-xAs量子阱相关的带间跃迁峰会出现红移。随着x的增加,短路电流密度增加,而开路电压降低。;此外,已经研究了在这些中带太阳能电池上使用廉价的减反射涂层(ARC)。基于氧化锌(ZnO)的减反射涂层显着提高了太阳能电池的功率转换效率。使用溶胶-凝胶技术合成的ZnO旋涂在太阳能电池上,然后进行退火。 ARC沉积后,短路电流密度显着增加。功率转换效率提高了42%左右。还观察到量子效率提高了约43%,光谱响应测量提高了44%。

著录项

  • 作者

    Vasan, Ramesh.;

  • 作者单位

    University of Arkansas.;

  • 授予单位 University of Arkansas.;
  • 学科 Alternative Energy.;Nanotechnology.;Engineering Electronics and Electrical.
  • 学位 M.S.
  • 年度 2013
  • 页码 60 p.
  • 总页数 60
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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