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Light-trapping structures based on low-melting point metals for thin-film solar cells

机译:基于低熔点金属的薄膜太阳能电池的陷光结构

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In this article, a new way based on low-melting-point metals is provided to fabricate light-trapping structures. Three classic metals, Al, Bi and Sn, are utilized to introduce textured topography. The fabrication technologies are quite simple that traditional evaporation is used here. The obtained textured Bi and Sn coatings are oxidized in air to be Bi2O3 and SnO2. Root-mean-roughness of over 100nm can be obtained, 120nm, 150nm and 142nm for Al, Bi2O3 and SnO2, respectively. Angle resolved scattering (ARS) of the coatings dependence on light scattering in air is compared and all the three coatings can scatter the incident light into large angles effectively. This indicates good light absorption in the subsequently deposited absorber layer. The three coatings are used as back reflectors and different silicon thickness from 300nm to 1200nm are sputtered on. The amorphous silicon is recrystallized by Cu induce crystallization. The reflectivity of the samples is tested by a spectrometer with an integrating sphere and average reflectivity (Ra) in the wavelength region from 400nm to 1100nm is discussed to reveal the light-trapping efficiency. The results presents that with only 300nm thick silicon layer, the Ra can be limited to 14% for the SnO2 coating. The Ra of Bi2O3 coated structure changes little when the silicon thickness changes between 480nm and 1200nm, and with only 480nm thick silicon layer, the Ra can be limited to 12%. For the textured Al coating, an optimal silicon thickness exists as 840nm and the Ra can be limited to nearly 10% at this point. We believe that the technologies are suitable for thin film solar cells for mass production.
机译:在本文中,提供了一种基于低熔点金属的新方法来制造光陷阱结构。三种经典金属Al,Bi和Sn用于引入织构形貌。制造技术非常简单,可以在这里使用传统的蒸发法。所获得的织构化的Bi和Sn涂层在空气中被氧化为Bi2O3和SnO2。可以得到超过100nm的均方根粗糙度,Al,Bi2O3和SnO2的均方根粗糙度分别为120nm,150nm和142nm。比较了涂层的角度分辨散射(ARS)对空气中光散射的依赖性,并且所有这三个涂层都可以有效地将入射光散射为大角度。这表明在随后沉积的吸收层中有良好的光吸收。这三个涂层用作背反射器,并在其上溅射300nm至1200nm不同的硅厚度。非晶硅通过Cu诱导结晶而重结晶。用具有积分球的光谱仪测试样品的反射率,并讨论了从400nm到1100nm波长范围内的平均反射率(Ra),以揭示光捕获效率。结果表明,只有300nm厚的硅层,SnO2涂层的Ra可以限制为14%。当硅厚度在480nm至1200nm之间变化时,Bi2O3涂层结构的Ra变化很小,而只有480nm厚的硅层,Ra可以限制为12%。对于有纹理的Al涂层,最佳硅厚度为840nm,此时Ra可以限制为接近10%。我们认为这些技术适用于薄膜太阳能电池的批量生产。

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