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Amorphous SiCN films prepared by ECR-CVD technique for photoconductive detectors

机译:通过ECR-CVD技术制备的用于光电导检测器的非晶SiCN膜

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Abstract: Amorphous silicon-carbon-nitrogen films prepared using the industry-used electron cyclotron resonance chemical vapor deposition technique at room temperature for photoconductive detectors are systematically investigate.d It is found that the film quality is sensitive to the preparation conditions. The deposition rate of the films is found to increase with the microwave power. It peaks at a ratio of silane to the mixture of silane, methane and nitrogen around 33 percent and at a radio frequency (RF) bias of 100 V. The otpical energy band-gap of the films increases monotonically with the gas ratio but decreases with RF bias. The conductivity of the materials is also found to vary with the preparation conditions. The change in the energy band-gap and conductivity is associated with the change in the incorporation of carbon and nitrogen. The wavelength in the range of 0.65 to 0.45 micron could be detected by controlling the deposition conditions. !11
机译:摘要:系统研究了采用工业用电子回旋共振化学气相沉积技术在室温下为光电导检测器制备的非晶硅碳氮薄膜。d发现薄膜质量对制备条件敏感。发现膜的沉积速率随着微波功率而增加。它在硅烷与硅烷,甲烷和氮的混合物的比例达到33%时达到峰值,并在100 V的射频(RF)偏压下达到峰值。薄膜的典型能带隙随气体比例单调增加,但随气体比例的增加而降低。射频偏置。还发现材料的电导率随制备条件而变化。能带隙和电导率的变化与碳和氮的结合变化有关。通过控制沉积条件可以检测到0.65至0.45微米范围内的波长。 !11

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