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Hydrogen-Related Effects in Oxides

机译:氧化物中与氢有关的效应

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摘要

Hydrogen exists in many as-grown oxide crystals as a ubiquitous impurity and can affect their electronic, mechanical, and optical properties [1-5]. Hydrogenic species (protons, deuterons and tritons) normally occupy stable configurations and do not diffuse until several hundred degrees above room temperautre [6,7]. In advanced energy systems, the hydrogen concentration is expected to increase dramatically when the ceramic oxide is exposed to high energy neutrons which induce different transmutation products [8]. The effects of such high levels of this impurity have not yet been investigated.
机译:氢以普遍存在的杂质形式存在于许多已生长的氧化物晶体中,并且会影响其电子,机械和光学特性[1-5]。产氢物质(质子,氘核和tri核)通常占据稳定的构型,直到室温以上数百度才扩散[6,7]。在先进的能量系统中,当陶瓷氧化物暴露于诱导不同trans变产物的高能中子时,氢浓度有望急剧增加[8]。如此高含量的这种杂质的影响尚未得到研究。

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