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(2439)STUDY OF A HIGH-TEMPERATURE RESISTANT PHTHALONITRILE RESIN SUITABLE FOR RTM PROCESSING AT LOW TEMPERATURES

机译:(2439)研究适用于低温下RTM加工的高温耐磷脂腈树脂

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One phthalonitrile resin system previously developed in our lab had a melting temperature around 160 °C, which was reported at SAMPE 2011. After modification, the resin started to melt around 100 °C and could maintain low viscosity at 130-140 °C for over 4 hours after mixed with catalyst, which was suitable for RTM. The processability of the resin system was studied by Rheometer. DSC and TGA were used to research the cure reaction and thermal properties, respectively. The relationship between glass transition temperature and curing temperature was studied by DMA technique. Preliminary study of mechanical properties of carbon fabric reinforced composite fabricated by RTM was carried out at room and elevated temperature. After the composite panel was cured to 375 °C, the retention rate of flexure strength was near 60 % at 400 °C and over 40% at 500 °C. The retention rate of short beam shear strength was over 60 % at 400 °C and above 40 % at 500 °C. All above demonstrated that this resin may be a good matrix for RTM and an excellent candidate for high performance polymeric materials.
机译:先前在我们的实验室中发育的一种酞酮腈树脂系统的熔化温度约为160℃,在Sampe 2011中报道。改性后,树脂开始熔化约100℃并可在130-140℃下保持低粘度与催化剂混合后4小时,适用于RTM。通过流变仪研究树脂体系的可加工性。 DSC和TGA分别用于研究固化反应和热性能。通过DMA技术研究了玻璃化转变温度和固化温度之间的关系。在室温下进行RTM制造的碳织物增强复合材料的力学性能初步研究,升高。将复合板固化至375℃后,弯曲强度的保持率在400℃下接近60%,在500℃下超过40%。短束剪切强度的保持率在400℃下超过60%,500℃高出40%。以上均证明该树脂可以是RTM的良好基质和高性能聚合物材料的优异候选物。

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