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Ultrasensitive biosensing based on plasmonic nanostructures

机译:基于等离子体纳米结构的超敏生物沉积

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Hafnium-doped zinc oxide (HZO) has been recently demonstrated to be implemented as a transparent conductingoxide (TCO) material in photovoltaic applications but its plasmonic properties are left untouched. In this work, wesystematically investigate the plasmonic properties of gold nanoparticle (Au NP) arrays on thin HZO film, for differentratios of Hf dopants to Zinc oxide (ZnO) film. A localized surface plasmon resonant (LSPR) mode and two Braggmodes (due to the coupling of plasmon modes inside the film to array periodicity) are observed in the proposedstructure. Resonant excitation of these modes produces large field enhancement at the surface of the NPs as well asAu NP/HZO film interface and was observed with FDTD simulations. The optimized plasmonic structure will befabricated on quartz crystal microbalance (QCM) using laser interference lithography, based on the plasmonicresonant position and the SERS (surface enhanced Raman scattering) intensity, and it will be integrated to amicrofluidic device in the configuration of the lab-on-a-chip concept for biosensing applications.
机译:最近已经证明了铪掺杂的氧化锌(HZO)作为透明导电光伏应用中的氧化物(TCO)材料,但其等离子体性能不受影响。在这项工作中,我们系统地研究金纳米颗粒(Au NP)阵列对薄HZO膜的等离子体性能,不同HF掺杂剂对氧化锌(ZnO)膜的比率。局部表面等离子体谐振(LSPR)模式和两个布拉格在提出的情况下,观察到模式(由于薄膜内部的等离子体模式的耦合)在提议中观察到结构体。这些模式的共振激励在NPS的表面产生大场增强,以及AU NP / HZO胶片接口,并用FDTD模拟观察。优化的等离子体结构将是基于等离子体,使用激光干扰光刻在石英晶体微稳态(QCM)上制造的谐振位置和sers(表面增强拉曼散射)强度,它将集成到一个微流体装置在构造中,用于生物传感应用的芯片概念。

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