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Derivative optical spectroscopy of thin films of alkaline-earth titanates: Critical points

机译:碱土钛酸薄膜的衍生光学光谱:关键点

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This paper analyzes UV Vis absorption spectra of amorphous thin films of barium strontium titanate (BST) deposited by RF magnetron sputtering on SiO_2 at different substrate temperatures. The Tauc procedure was used to determine optical band gaps for direct and indirect interband transitions. This procedure was accompanied by derivative spectroscopy useful in case of multicomponent systems. Higher-order derivatives were used to find the so-called critical points related to the optical interband transitions at various regions in the Brillouin zone. Three critical points were identified in BST thin films spectra of dielectric function. All optical band gaps and energies of critical points were found to decrease with the substrate temperature at the deposition.
机译:本文分析了在不同基板温度下SiO_2沉积的RF磁控溅射钡锶锶钡(BST)的无定形薄膜UV Vis吸收光谱。 SUC过程用于确定用于直接和间接的间带间转换的光带间隙。该方法伴随着在多组分系统的情况下可用的衍生光谱。使用高阶导数来找到与布里渊区的各个区域的光学间隙转换相关的所谓的关键点。在介质函数的BST薄膜光谱中鉴定了三个关键点。发现所有光学带间隙和关键点的能量随着沉积的底物温度而减小。

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