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Structural and optical studies on spin coated ZnO-Graphene conjugated thin films

机译:旋涂ZnO-石墨烯共轭薄膜的结构和光学研究

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ZnO-Graphene conjugated thin films were prepared using spin coating technique for different spin rates. Prior to the deposition, ZnO-Graphene nanoparticles were synthesized and their particle size and conjugation was studied through Transmission electron microscope (TEM). The deposited films were characterized using grazing incidence x-ray diffractometer (GIXRD), atomic force microscope (AFM) and UV-Visible spectrometer for their crystallinity, surface topographic features and optical properties. GIXRD patterns confirms the presence of both ZnO and Graphene related crystalline peaks supports the TEM results, which shows the quasi core-shell type conjugation of ZnO-Graphene particles. The crystallinity as well as thickness of the films found to decrease with increase of spin rate. AFM results reveal the uniform, smooth and homogeneity of films and also good adhesivity of ZnO-Graphene with glass substrates. No significant change in the transmittance and absorption with spin rate is observed, while the band gap energy found to decrease due to the reduction in the thickness of the films and conjugation of ZnO-Graphene. All films exhibit~ 90 % transmittance in the visible wavelength region, could be potential candidates for optoelectronics and transparent conducting oxide (TCO) applications.
机译:使用旋涂技术制备ZnO-石墨烯共轭薄膜,用于不同的旋转速率。在沉积之前,合成ZnO-石墨烯纳米颗粒,并通过透射电子显微镜(TEM)研究其粒度和缀合。使用放牧入射X射线衍射仪(GixRD),原子力显微镜(AFM)和UV可见光光谱仪的沉积膜的特征在于,其结晶度,表面形貌特征和光学性质。 GixRD图案证实存在ZnO和石墨烯相关的结晶峰的存在支持TEM结果,其表示ZnO-石墨烯颗粒的准核 - 壳型缀合。结晶度以及薄膜的厚度随着旋转速率的增加而降低。 AFM结果揭示了薄膜的均匀,平滑和均匀性,以及ZnO-石墨烯的良好粘附性与玻璃基板。没有观察到透射率和旋转速率的显着变化,同时由于薄膜厚度和ZnO-石墨烯的缀合而导致的带隙能量降低。所有薄膜在可见波长区域中表现出〜90%的透射率,可以是光电子和透明导电氧化物(TCO)应用的潜在候选。

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