Study on structural, linear and nonlinear optical properties of spin coated N doped CdO thin films for optoelectronic applications

摘要

AbstractThe work in current article deals with the fabrication of pure and Nitrogen (N) doped (1–20%) Cadmium oxide thin films using sol–gel spin coating processes. The characteristic peak (200) was identified in X-ray diffraction profiles. The grain size and surface roughness values are found to be 7.52?nm, 7.68?nm, 7.89?nm, 7.91?nm, 8.02?nm, 8.05?nm and 15.02?nm, 15.23?nm, 15.31?nm, 15.42?nm, 16.05?nm, 16.06?nm for respective films. The induced vibrational modes were analysed by the Raman spectroscopy. Optical parameters were determined using transmittance, reflectance and absorption spectra. The optical transparency of the fabricated films is observed to be very high (i.e. >80%) and optical band gap is in range of 3.92–3.98?eV. Moreover, nonlinear refractive index (n2) and third order nonlinear susceptibility (χ3) was also calculated and found to be in the range of 2.80?×?10?12to 1.01?×?10?8and 1.31?×?10?13to 1.24?×?10?9?esu.Graphical abstractDisplay OmittedHighlights?Pure and N doped high quality CdO films were deposited by Spin coating technique.?UV-Vis-NIR measurement confirms high optical transparency of pure and doped films.?Direct optical band gap was calculated and found in the range of 3.92 - 3.98 eV.?Strong effect of N doping on third order nonlinear properties are observed.?The values ofn2andχ3are found to be of order of 10-8and 10-9esu, respectively.]]>