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Dynamic Anomalies in Confined Supercooled Water and Bulk Fluids

机译:紧密过冷水和散装液中的动态异常

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This review paper is aimed at studying the problems as follows: (1) the Widom line and its analogues in supercooled and supercritical regions; (2) effects of dimensional crossover (DC) on the critical exponents, effective spatial d_(eff) and fractal d_(fr) dimensionalities; (3) anomalous behavior of the diffusion coefficient D and the shear viscosity coefficientηin bulk fluids and confined supercooled water (CSW) near the critical points; (4) spectra of the light molecular scattering (LMS) and quasi-elastic neutron scattering (QENS) and its possible medical applications. The effective critical exponents as well as the effective spatial d_(eff) and fractal d_(fr) dimensionalities were calculated for confined fluids like CSW. A3d ?2d DC between the critical exponents α= 0,β=1/8,δ=15,γ=7/4,v=1 and α= 0.110,β= 0.3265, δ= 4.789,γ=1.237,v=0.630 for 2d and 3d systems belonging to the Ising-model universality class were taken into account. Anomalies of the diffusion coefficient were examined in bulk water and CSW in wide intervals of the size and thermodynamic variables corresponding to crossover phenomena between the dynamic fluctuation, crossover and regular regions. The transition between dynamic crossover and regular regions in bulk fluids, including bulk water, is illustrated by changes in the diffusion-coefficient dependences on: (a) the size variable-from D~ L~(-1.963) to D~ L~(-2), (b) the temperature variable-from D~ (T - Tc)~(1. 237) to D~ (T - Tc), (c) the concentration variable-from D~ (x - x_c)~(3.789) to D~ (x - x_c)~2, (d) the pressure variable D~ (p - p_c)~(0.791) to D~ (p - Pc)~(0.667.) In confined 2d fluids like CSW such a transition between crossover and regular behaviors should be treated as 2d? 4d crossover phenomena because results of the Landau mean-field theory are valid for d= 4 (with a logarithmic accuracy). A 2d ? 4d crossover leads to the following changes in dependence of the diffusion coefficient D on: (a) the size variable from D~ L~(
机译:这篇综述本文旨在研究如下的问题:(1)代表智慧线及其在过冷和超临界区的类似物; (2)在临界指数维交叉(DC),有效的空间D_(EFF)和分形D_(FR)维度的影响; (3)中的扩散系数d和接近临界点的剪切粘度coefficientηin散装流体和限制过冷水(CSW)的异常行为; (4)的光散射的分子(LMS)和准弹性中子散射(QENS)及其可能的医学应用的光谱。有效临界指数以及有效空间D_(EFF)和分形D_(FR)的维度,分别计算像CSW密闭流体。 A3D?2d的DC临界指数之间α= 0,β= 1/8,δ= 15,γ= 7/4,V = 1和α= 0.110,β= 0.3265,δ= 4.789,γ= 1.237,V = 0.630对于属于伊辛模型普适类的二维和三维系统被考虑在内。扩散系数的异常在大体积的水和CSW在尺寸的宽区间和相应的,交叉的动态波动,交叉和常规区之间现象热力学变量进行了检查。 (a)所述大小可变从d〜L〜(-1.963)至d〜L〜(:动态交叉和在散装流体定期区域,包括大体积的水之间的过渡是通过在在扩散系数依赖性的变化示出的-2),(b)中的温度可变从d〜(T - TC)〜(1 237)到d〜(T - TC),(C)的浓度可变从d〜(X - x_c)〜 (3.789)到d〜(X - x_c)〜2,(d)中的压力可变d〜(对 - P_C)〜(0.791)到d〜 - (对PC)〜(0.667)在狭窄2d中的流体等CSW交叉和常规行为之间这种转变应被视为2D?图4d交叉现象,因为兰道平均场理论的结果是有效的d = 4(具有对数的准确度)。二维?图4d交叉导致在扩散系数d的上依赖下列的变化:(a)由d〜L〜大小可变(

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