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Synthesis and characterization of silicon-containing arylacetylene ether of bisphenol a resins and their composites

机译:双酚A树脂含硅芳基芳基芳基乙炔醚的合成与表征及其复合材料

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Two novel resins, silicon-containing arylacetylene ether of bisphenol A (PSAP-A) and 1,3-diethynylbenzene-terminatedsilicon-containing arylacetylene ether of bisphenol A (DPSAP-A), were synthesized from dipropargyl ether of bisphenol A (BADPE) and dimethyldichlorosilane through Grignard reaction. The structures of the resins were characterized by protonnuclearmagnetic resonance(~1H-NMR), and thermal properties was explored by thermogravimetric analysis(TGA)and dynamic thermo-mechanical analysis (DMA). In addition, T300 carbon fiber(T300CF) reinforced PSAP-A composite (T300CF/PSAP-A)and T300 carbon fiber reinforced DPSAP-A composite (T300CF/DPSAP-A) . were prepared by a solution-impregnation process using tetrahydrofuran as solvent. The results showed that the cured PSAP-A resin and DPSAP-A resin displayed good heat resistance and processing properties. Degradation temperatures of the cured PSPA-A resin and DPSAP-A resin at 5% weight loss (T_(d5)) were 421.5°C and 486.3°C, respectively. The flexural strengths of T300CF/PSAP-A and T300CF/PSAP-Acomposites reached 458.2 MPa and 287.6 MPa, respectively.
机译:两个新的树脂,双酚A(PSAP-A)和1,3-二乙炔含terminatedsilicon - 双酚A(DPSAP-A)的芳基乙炔醚,购自双酚A(BADPE)的二炔丙基醚合成的含硅芳基乙炔醚通过格利雅反应二甲基二氯硅烷。通过protonnuclearmagnetic共振(〜1H-NMR)的树脂的结构进行了表征,性质和热性质是通过热重分析(TGA)和动态热机械分析(DMA)的探讨。另外,T300碳纤维(T300CF)增强PSAP-A复合物(T300CF / PSAP-A)和T300碳纤维增强DPSAP-A复合物(T300CF / DPSAP-A)。通过使用四氢呋喃作为溶剂中的溶液浸渍方法制备。结果表明,固化的PSAP-A树脂和DPSAP-A树脂显示出良好的耐热性和加工性能。在5个%重量损失(T_(D5))固化PSPA-A树脂和DPSAP-A树脂的降解温度分别为421.5℃,486.3℃。 T300CF / PSAP-A和T300CF的挠曲强度/ PSAP-Acomposites分别达到458.2兆帕和287.6兆帕。

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