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Mossbauer Investigation of the Chelyabinsk Meteorite Fragment

机译:Chelyabinsk陨石片段的Mossbauer调查

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The article devoted to study of the fragments of Chelyabinsk meteorite with the help of Mossbauer spectroscopy. It is shown that the iron in various fragments of the meteorite exist in different crystallographic, physical and chemical conditions. A new phenomenon of sharp increasing effective magnetic field in the region of the iron nuclei in the temperature range of 553-573 K and jumps of the main parameters of Mossbauer spectra at other temperatures are observed. According to the data of the isomer shifts and quadruple splitting of the individual spectra, iron ions have a valence of Fe~(2+)- 3d~6, Fe~(3+)- 3d~5, Fe~(4+)- 3d~4, Fe~(6+) - 3d~2 and also intermediate between them. A qualitative explanation of the experimental data is proposed.
机译:本文致力于研究Chelyabinsk Meteorite的碎片在莫斯堡光谱的帮助下。结果表明,陨石各种碎片中的铁存在于不同的晶体,物理和化学条件下。观察到在553-573k的温度范围内的铁核区域中急剧增加有效磁场的新现象,并在其他温度下捕获母蛋白光谱的主要参数跳跃。根据异构体偏移和四重分裂的单独光谱的数据,铁离子具有Fe〜(2 +) - 3D〜6,Fe〜(3 +) - 3D〜5,Fe〜(4+)的价值 - 3D〜4,Fe〜(6+) - 3D〜2,以及它们之间的中间。提出了对实验数据的定性解释。

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