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Optical Study of Chemically Synthesized Conducting Polythiophene Using UV-Vis Spectroscopy

机译:使用UV-Vis光谱化学合成的化学合成聚噻吩的光学研究

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This research article was intended to examine the optical properties of as- synthesized conducting polythiophene (PTh). Thiophene, the monomer of PTh, has been polymerized through chemically oxidative polymerizationmethod in the presence of an oxidant anhydrous ferric chloride (FeCl3). The surface morphology of prepared sample was analyzed through FE-SEM, which shows irregular structure and spongy amorphous morphology. The UV-vis spectroscopy was performed to study optical parameters. This polymeric material exhibited absorption around 200-250 nm. The optical band gap energy values of prepared samples ranges over 4.033-4.688 eV. The estimated optical band gap energy has accepted value for photovoltaic activities and has potential for application in solar cells and optical devices.
机译:该研究制品旨在检测合成的导电聚噻吩(PTH)的光学性质。噻吩,Pth的单体通过化学氧化聚合方法在氧化剂无水氯化物(FECL3)存在下聚合。通过Fe-SEM分析制备样品的表面形态,其显示不规则结构和海绵状无定形形态。进行UV-Vis光谱学研究光学参数。该聚合物材料在200-250nm左右表现出吸收。制备样品的光带间隙能量值超过4.033-4.688eV。估计的光带间隙能量已接受光伏活动的值,并且具有在太阳能电池和光学器件中应用的潜力。

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