Preparation and performance of self-healing epoxy composites by microcapsulated approach

摘要

Microencapsulated E-51 epoxy resin healing agent and phthalic anhydride latent curing agent were incorporated into E-44 epoxy matrix to prepare self-healing epoxy composites. When cracks were initiated or propagated in the composites, the microcapsules would be damaged and the healing agent released. As a result, the crack plane was healed through curing reaction of the released epoxy latent curing agent. In the paper, PUF/E-51 microcapsules were prepared by in-situ polymerization. The mechanical properties of the epoxy composites filled with the self-healing system were evaluated. The impact strength and self-healing efficiency of the composites are measured using a Charpy Impact Tester. Both the virgin and healed impact strength depends strongly on the concentration of microcapsules added into the epoxy matrix. Fracture of the neat epoxy is brittle, exhibiting a mirror fracture surface. Addition of PUF/E-51 microcapsules decreases the impact strength and induces a change in the fracture plane morphology to hackle markings. In the case of 8.0 wt% microcapsules and 3.0 wt% latent hardener, the self-healing epoxy exhibited 81.5% recovery of its original fracture toughness.