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Optical Studies of poly (N-carbazole) (PVK) Blending With Polyvinylpyrrolidone (PVP) Using Tauc/Davis-Mott Model

机译:使用Tauc / Davis-Mott模型与聚乙烯吡咯烷酮(PVP)混合的聚(N-咔唑)(PVK)的光学研究

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The optical absorption spectra of blended poly (N-carbazole) (PVK) with polyvinylpyrrolidone (PVP) in various compositions are investigated. A doctor blade technique was used to coat the blended polymer on a quartz substrate. The electronic parameters such as absorption edge (E_e), allowed direct band gap (E_d), allowed indirect band gap (E_i), Urbach edge (E_u) and steepness parameter (γ) were calculated using Tauc/Davis-Mott Model. The results reveal that the E_e, Ed and E_i increase with increasing of PVP ratio. There also have variation changing in Urbach energy and steepness parameter.
机译:研究了各种组合物中具有聚乙烯吡咯烷酮(PVP)的共混聚(N-咔唑)(PVK)的光学吸收光谱。使用刮刀技术在石英底物上涂覆混合聚合物。使用Tauc / Davis-Mott模型计算诸如吸收边缘(E_E),允许的间接带隙(E_I),URBACH边缘(E_U)和陡峭参数(γ)的电子参数。结果表明,随着PVP比率的增加,E_E,ED和E_I增加。在URBACH能量和陡度参数中也有变化变化。

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