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Preparation of Red-emitting Europium(III) doped SrAl_2B_2O_7 Phosphors and Investigation of Luminescent Properties

机译:制备红发铕(III)掺杂SRAL_2B_2O_7磷光体和发光特性的研究

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Red-emitting Europium(III) doped SrAl_2B_2O_7 phosphors have been prepared by precipitation method, and its luminescent properties under UV excitation have been investigated. The phosphors are characterized by X-ray diffraction (XRD) and photoluminescence spectra. The SrAl_2B_2O_7:Eu~(3+) phosphors can be obtained at 900°C by calcining precipitation precursor. These phosphors can be effectively excited by UV light at 394nm. In emission spectra, the strongest peak at 618 nm correlating to red emission is due to the electric dipole transition ~5D_0→~7F_2 of Eu~(3+) ions. The luminescent properties of SrAl_2B_2O_7:Eu~(3+) phosphors with 8 mol% doping concentration of Eu~(3+) are optimal.
机译:通过沉淀法制备红发射铕(III)掺杂的SRAL_2B_2O_7磷光体,并研究了紫外线激发下的发光性能。磷光体的特征在于X射线衍射(XRD)和光致发光光谱。 SRAL_2B_2O_7:EU〜(3+)磷光体可以通过煅烧沉淀前体在900℃下获得。这些磷光体可以通过394nm的UV光有效激发。在发射光谱中,618nm处的最强峰与红色发射相关的是由于Eu〜(3+)离子的电偶极转变〜5d_0→〜7f_2。 SRAL_2B_2O_7的发光特性:EU〜(3+)eu〜(3+)掺杂浓度为8mol%掺杂浓度的磷光体是最佳的。

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