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Protective Coatings for Metallic Components in SOFC Systems

机译:SOFC系统中金属组分的保护涂层

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As solid-oxide fuel cells near commercialization a key barrier to widespread adoption is the high cost of the technology. The U.S. Department of Energy cost goal of $700/kW for SOFC power generation systems requires the selection, wherever possible, of common grade stainless steel into the stack design, including the "balance of plant" components (gas manifolding and delivery, thermal management equipment, fuel processors, and compression systems) as well as the high temperature stack itself (metallic interconnects). Chromia forming steel and nickel-based alloys have been traditionally used for fabricating these components. However, without protective coatings, the air-facing surfaces of steel components oxidize and volatize chromium species that poison the stack. Similarly, air/exhaust heat exchangers must be designed to prevent chromium volatilization; on the fuel side, oxidation (due to high steam content gas streams), carburization and coking are all catastrophic failure mechanisms for metals facing high carbon fuel streams.
机译:作为商业化附近的固体氧化物燃料电池,广泛采用的关键屏障是该技术的高成本。美国的能源成本目标为700美元/千瓦的SOFC发电系统需要选择,无论何处,共用等级不锈钢都进入堆叠设计,包括“植物平衡”组件(气体渠道和输送,热管理设备,燃料处理器和压缩系统)以及高温堆叠本身(金属互连)。形成铬形成钢和镍基合金传统上用于制造这些组分。然而,没有防护涂料,钢结构的空心表面氧化和挥发铬物种毒物堆叠。类似地,空气/排气热交换器必须设计成预防铬挥发;在燃料侧,氧化(由于高蒸汽含量气流),渗碳和焦化是对高碳燃料流面临的金属灾难性的故障机制。

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