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EFFECT OF MWNT-DISPERSION IN NBR-COMPOUNDS

机译:MWNT-分散在NBR-化合物中的影响

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摘要

Multiwall carbon nanotubes (MWNT) are an innovative raw material, coming into the market in larger quantities of several hundred metric tons per year. Carbon nanotubes (CNT) display extraordinary physical properties, such as very high electrical and thermal conductivity combined with the immense strength of the individual nanotube. The challenge involved in using this innovative raw material for rubber products is to transfer the properties of one single nanotube from the microscopic range to a macroscopic composite material, the most critical factors being the careful dispersion of the "entangled" nanotube agglomerates and their uniform distribution in a rubber matrix. Like for conductivity carbon blacks the homogeneity of the CNT filled rubber compounds increases with rising mixing time in an internal mixer while the electrical conductivity decreases. With an innovative mixing technique CNT-masterbatches with a high degree of agglomerate dispersion have been obtained. Using these masterbaches NBR-vulcanisates are very homogeneous and electrically conductive at the same time. Stress values at 300% of 8 MPa at 10 phr filler loading indicate the strong reinforcement potential of this new filler type.
机译:多壁碳纳米管(MWNT)是一种创新的原料,每年进入大量数百公吨的市场。碳纳米管(CNT)显示出非凡的物理性质,例如非常高的电导率和导热性与各个纳米管的巨大强度相结合。使用这种创新原料的橡胶产品所涉及的挑战是将一个单一纳米管的性质从显微镜范围转移到宏观复合材料,最关键的因素是“缠绕”纳米管附聚物的仔细分散及其均匀分布在橡胶基质中。类似于电导率炭黑,CNT填充橡胶化合物的均匀性随着在内部混合器中上升的混合时间而增加,而导电性降低。通过创新的混合技​​术,已经获得了具有高凝聚分散体的CNT-母料。使用这些MasterBaches NBR-硫化酸盐同时非常均匀和导电。在10 phr填充荷载荷为8MPa的300%的应力值表明该新填充型的强度强化潜力。

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