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Study of Raman Spectrum of Fe Doped CeO_2 Thin Films Grown by Pulsed Laser Deposition

机译:脉冲激光沉积生长Fe掺杂CEO_2薄膜的RAMAN光谱研究

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Ce_(1-x)Fe_xO_2 (x=0, 0.01, 0.03 and 0.05) thin films were grown by pulsed laser deposition technique on Si and LaAlO_3 (LAO) substrates. These films were deposited in vacuum and 200 mTorr oxygen partial pressure for both the substrates. These films were characterized by x-ray diffraction XRD and Raman spectroscopy measurements. XRD results reveal that these films are single phase. Raman results show F_(2g) mode at ~466 cm~(-1) and defect peak at 489 cm~(-1) for film that deposited on LAO substrates, full width at half maximum (FWHM) is increasing with Fe doping for films deposited on both the substrates.
机译:CE_(1-x)Fe_XO_2(x = 0,0.01,0.03和0.05)薄膜通过Si和LaAlo_3(Lao)基板上的脉冲激光沉积技术生长。将这些薄膜沉积在真空和200mtorr氧分压中的底物。这些薄膜的特征在于X射线衍射XRD和拉曼光谱测量。 XRD结果表明,这些薄膜是单相。拉曼结果显示F_(2g)模式在〜466cm〜(-1)和489cm〜(-1)的缺陷峰值,用于沉积在老挝基板上的薄膜,半宽(fwhm)的全宽与fe掺杂增加薄膜沉积在衬底上。

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