Poly(pyrroles) grafted by chiral side chains: new results on the effect of substituents of the enantioselective properties in the doped as well as in the undoped state of the polymer films

摘要

The dependence of the absolute configuration of the chiral C-atom on the chiral discrimination is visible from the results obtained at undoped (R)- and (S)-configurated poly(pyrroles) grafted by chiral side chains ((R)-poly-1, (S)-poly-1). The chiral discrimination is also influenced by the position of the carbonyl group in the side chain as demonstrated comparing the results obtained at doped and undoped poly-3 and poly-4.