Linear polymers with hyperbranched side chains via the 'hypergrafting' strategy:a simulation study and first synthetic results

摘要

The combination of dendritic structures and linear polymers has met increasing interest in recent years.For instance,AB block copolymers with a linear A-block and a dendritic B block have been studied by several authors.Dendronized polymers,i.e.,linear polymer chains with perfect dendritic side chains (dendrons) are being investigated by numerous groups,demonstrating that such macromolecules form unusually rigid nano-objects (Scheme 1).