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Methods of suppressing cluster growth in silane RF discharges

机译:抑制硅烷RF放电簇生长的方法

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The effects of gas temperature gradient, pulse discharge modulation, hydrogen dilution, gas flow, and substrate materials on growth of clusters below about 10 nm in size in silane parallel-plate RF discharges are studied using a high-sensitivity photon-counting laser-light-scattering (PCLLS) method. Thermophoretic force due to the gas temperature gradient between the electrodes drives neutral clusters above a few nm in size toward the cool RF electrode. Pulse discharge modulation is much more effective in reducing the cluster density when it is combined with the gas temperature gradient, and clusters above a few nm in size cannot be detected by the PCLLS method even for the discharge over a few hours. Hydrogen dilution and gas flow are also effective in suppressing growth of clusters, when the H{sub}2/SiH{sub}4 concentration ratio is above about 5 and the flow velocity is above about 6 cm/s, respectively. Cluster growth rate with a glass or Si substrate is found to be considerably higher than that without the substrate.
机译:使用高灵敏度光子计数激光光进行了研究气体的温度梯度,脉冲放电调制,氢稀释,气体流量,和衬底材料上在硅烷平行板RF放电尺寸低于约10纳米团簇的生长的影响-scattering(PCLLS)方法。热泳力由于电极之间的气体的温度梯度驱动上述在朝向凉RF电极尺寸为几纳米中性团簇。脉冲放电调制是在减少的群密度时,它与气体温度梯度组合,并且上述的尺寸为几纳米簇不能被PCLLS方法即使对于放电过了几个小时来检测有效得多。氢稀释和气体流量也有效地抑制簇的增长,当H {}子2 / SiH基{子} 4浓度比为高于约5和流速是上述分别约为6厘米/秒。与玻璃或Si基板簇生长速率被发现是比相当高的无基材。

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