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Resonant Intermolecular Energy Transfer in Liquid Water

机译:液态水中的共振分子能量转移

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We report on the observation of resonant vibrational energy transfer in a liquid at room temperature. This resonant energy transfer process is observed to occur for the O-H stretch vibration in solutions of HDO in D_2O and in neat liquid water (H_2O). For solution of HDO in D_2O, the energy-transfer can be quantitatively described with a model in which the O-H groups are coupled via dipole-dipole interactions. Surprisingly, this description strongly underestimates the rate of energy transfer thatn is observed for neat liquid water, which indicates the presence of additional interaction mechanisms.
机译:我们报道了在室温下液体中谐振振动能量转移的观察。观察到该共振能量转移过程是为了在D_2O和整齐的液态水(H_2O)中HDO溶液中的O-H拉伸振动。对于在D_2O中的HDO溶液中,可以通过偶极偶极相互作用来定量地描述能量转移,其中O-H基团通过偶极偶极相互作用偶联。令人惊讶的是,这种描述强烈低估了对整个液体水观察到的能量转移速率,这表明存在额外的相互作用机制。

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