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Polymeric and Ceramic Nanofibers from Novel Gas Jet Fiber Spinning

机译:新型气体喷射纤维纺丝聚合物和陶瓷纳米纤维

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One dimensional (1-D) nanofibers can play a vital role in the fields of filtration, opto-electronic, sensor, solar cell, catalysis etc. Here, we demonstrate a novel Gas Jet Fiber (GJF) spinning process for fabrication of polymeric and ceramic nanofibers with controlled morphologies and size. The current technique can produce fibers with higher production rate, at least 30 times higher for the same fiber diameter compared to single jet electrospinning. For example, titanium dioxide (TiO2) nanofibers of diameter ca. 50-300 nm are fabricated by calcining at 500-700 °C in air. The nanofibers are obtained from spinning solutions of polyvinylpyrrolidone (PVP) and titanium isopropoxide (TTIP). The morphology and chemical structure of the precursor polymer and calcined fibers are characterized by scanning electron microscopy (SEM), thermo gravimetric analysis (TGA), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Furthermore, GJF-spun core-shell and side-by-side morphologies of polymer nanofibers such as polyvinyl acetate (PVAc)-polyethylene oxide (PEO) and PVP-PEO are also demonstrated.
机译:一维(1-D)纳米纤维可以在过滤,光电,传感器,太阳能电池,催化等领域发挥重要作用。在此,我们展示了一种用于制造聚合物的新型气体喷射纤维(GJF)纺纱方法和陶瓷纳米纤维具有受控形态和尺寸。与单喷射静电纺丝相比,目前的技术可以产生具有较高生产率的纤维,相同的纤维直径至少30倍。例如,直径Ca的二氧化钛(TiO 2)纳米纤维。通过在空气中煅烧500-700°C来制造50-300nm。纳米纤维是从聚乙烯吡咯烷酮(PVP)的纺丝溶液和钛等原子氧化钛(TTIP)获得的。通过扫描电子显微镜(SEM),热重分析(TGA),透射电子显微镜(TEM)和X射线衍射(XRD),表征前体聚合物和煅烧纤维的形态和化学结构。此外,还证明了聚合物纳米纤维的GJF-Spun核心 - 壳和旁边形貌,例如聚乙酸乙烯酯(PVAC) - 聚环氧丙烷(PEO)和PVP-PEO。

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