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Influence of Polymer Structural Conformation and Phase Behaviour on In-situ Viscosity

机译:聚合物结构构象和相行为对原位粘度的影响

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Polymer flooding is primarily implemented to accelerate oil production by sweep improvement and/or to reduce oil-water mobility ratio in heavy oil fields. During the last decade it has been evaluated for an increasing number of fields, both offshore and onshore. Although it is a mature EOR (Enhanced Oil Recovery) method, there are still a number of challenges with respect to describing polymer flow in porous media. This increases uncertainty and risk in planning and evaluation of polymer flood projects. A key issue is the prediction of in-situ viscosity. This study evaluates in-situ viscosity from the perspective of the different conformational states or phase behaviour classes of a typical synthetic polymer, HPAM (partially hydrolysed polyacrylamide). In-situ viscosity is determined as a function of concentration, molecular weight and salinity. The main objective is to improve the description and prediction of in-situ viscosity based on a classification of polymer phase behaviour. The experiments were performed using low and high molecular weight HPAM polymers dissolved in two different brines. In-situ viscosity was determined by core floods for 4 different concentrations in the dilute, semi-dilute, concentrated and gel solution regimes. The results reveal how salinity is a dominating factor for in-situ viscosity in the dilute and semi-dilute concentration regime, but is less important at higher concentrations. In the upper semi-dilute and concentrated regimes, molecular weight is the dominating factor for in-situ viscosity', but show an unexpected trend with regard to shear. The results also give insight on the influence of polymer elasticity on resistance factor (RF) and the influence of molecular weight. salinity and polymer concentration on residual resistance factor (RRP). The presented work show that the polymer conformational state should be considered when designing field implementation of polymer flooding.
机译:聚合物驱油主要是实现由扫改善加速油产量和/或降低重油油田油 - 水流动性比。在过去十年中已经评估了越来越多的领域,无论是海上和陆上。虽然这是一个成熟的EOR(强化采油)的方法,仍然存在许多挑战相对于描述在多孔介质中的聚合物流。这增加了不确定性和风险规划和聚合物驱项目的评价。一个关键问题是原位粘度的预测。本研究评估原位粘度从典型的合成聚合物,聚丙烯酰胺(部分水解的聚丙烯酰胺)的不同构象状态或相行为的类的角度。原位粘度被确定为浓度,分子量和盐度的函数。其主要目的是改善原位粘度的基础上的聚合物相行为分类的描述和预测。该实验使用溶解在两个不同的低的盐水和高分子量聚合物HPAM执行。原位粘度通过对4种不同浓度的稀的,半稀岩心驱替,浓缩,凝胶溶液制度测定。结果表明盐度是如何在稀释及半稀释浓度政权原位粘度的主导因素,但在较高浓度不那么重要了。在上半稀,并浓缩制度,分子量是占主导地位的因子用于原位粘度”,但显示出对于剪切意想不到的趋势。结果也给聚合物弹性的导通电阻因子(RF)和分子量的影响的影响的洞察力。上残余阻力系数(RRP)盐度和聚合物浓度。该论文显示,聚合物构象状态应该设计聚合物驱油现场实施时予以考虑。

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