ORGANOCATALYTIC STEREOSELECTIVE SYNTHESIS OF 2-DEOXYGLYCOSIDES

摘要

The biggest challenge within oligosaccharide synthesis is the stereoselective control of glycosidic linkages. Neighbouring group participation (NGP) offers the most reliable method for stereoselective glycosylations; however, the incorporation and the use of NGP groups can be laborious and sometimes not applicable to all types of monosaccharides e.g. 2-deoxyglycosides.