Moessbauer spectra of Eu(Ⅲ) and Gd(Ⅲ) complexes of phosphine oxides with chelating perchlorate

机译：欧盟（Ⅲ）和Gd（Ⅲ）复合物的Moessbauer光谱螯合螯合高氯酸盐

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The reaction of Ln(ClO_4)_3 · nH_2O with triphenylphosphine oxide (TPPO) in methanol has led to the formation of [Ln(ClO_4)_2(tppo)_4]ClO_4-MeOH (Ln = Nd, Eu, Gd, Dy, Yb), in which the perchlorate anion acts as a symmetric bidentate. The emission spectra of Eu(Ⅲ)-TPPO complexes, showing enhancement in the intensity due to the phenyl group, indicate an isotropic electron distribution for the nitrato complex [Eu(NO_3)_3(tppo)_2(EtOH)]. ~(151)Eu and ~(155)Gd Moessbauer spectra of the TPPO complexes also lead to the same conclusion.

机译：LN（CLO_4）_3·NH_2O与三苯基膦氧化物（TPPO）的反应导致[LN（CLO_4）_2（TPPO）_4] CLO_4-MEOH（LN = ND，EU，GD，DY，YB ），其中高氯酸盐阴离子充当对称的二齿。 Eu（Ⅲ）-TPPO复合物的发射光谱，显示由于苯基引起的强度增强表明亚硝酸盐复合物[EU（NO_3）_3（TPPO）_2（EtOH）]的各向同性电子分布。〜（151）欧盟和〜（155）GD Moessbauer的TPPO复合物的光谱也导致得出相同的结论。

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《International conference on the applications of the Mossbauer effect》|2012年||共4页
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Masashi Takahashi; Yuya Hirai;
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中图分类原子核物理学;
关键词
lanthanide complex; phosphine oxide; perclorato complex; emission spectra; moessbauer spectra;

机译：镧系元素;氧化膦;perclorato复合物;排放光谱;Moessbauer光谱;

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1. Mössbauer spectra of Eu(III) and Gd(III) complexes of phosphine oxides with chelating perchlorate [J] . Masashi Takahashi, Yuya Hirai Hyperfine Interactions . 2012,第1a3期

机译：氧化膦与螯合高氯酸盐的Eu（III）和Gd（III）配合物的Mössbauer光谱
2. Mossbauer spectra of Eu(III) and Gd(III) complexes of phosphine oxides with chelating perchlorate [J] . Masashi Takahashi, Yuya Hirai Hyperfine Interactions: Journal Devoted to Research in the Border Regions of Solid State, Atomic and Nuclear Physics . 2011,第1a3期

机译：氧化膦与螯合高氯酸盐的Eu（III）和Gd（III）配合物的Mossbauer光谱
3. Effect of free and chelating phosphine coordination environments on the NiS2P2 chromophore: synthesis, NMR and other spectral studies. Crystal and molecular structures of (N,N-dipropyldithiocarbamato)di(triphenylphosphine)nickel(II) perchlorate and ( [J] . Prakasam BA, Ramalingam K, Saravanan M, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2004,第1期

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4. Moessbauer spectra of Eu(Ⅲ) and Gd(Ⅲ) complexes of phosphine oxides with chelating perchlorate [C] . Masashi Takahashi, Yuya Hirai International conference on the applications of the Mossbauer effect . 2012

机译：欧盟（Ⅲ）和Gd（Ⅲ）复合物的Moessbauer光谱螯合螯合高氯酸盐
5. I. New routes to the synthesis of chelating phosphines for use in hydroformylation catalysis. II. Organometallic complexes of convex hydrocarbons [D] . Misquitta, Barry J. 2000

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8. Moessbauer Study of Some Iron (III) Complexes with Urea-Type Ligands and Crystal Structure of Hexakisdimethylurea Iron (III) Perchlorate [R] . Calogero, S., Galeazzi, G., Russo, U., 1980

机译：moessbauer研究一些具有尿素型配体的铁（III）配合物和Hexakisdimethylurea铁（III）高氯酸盐的晶体结构

Moessbauer spectra of Eu(Ⅲ) and Gd(Ⅲ) complexes of phosphine oxides with chelating perchlorate

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