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Deconvolution of Isobaric Interference in ICP-MS by Peak Shape Calibration Technology

机译:峰形校准技术对ICP-MS中同学干扰的折应

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With peak shape calibration performed with As standard, symmetrical and mathematical well defined peak shape can be obtained for all ICP-MS spectra for the mixtures of As spiked with [Cl~(-)] and allows accurate spectral deconvolution and quantitation of the mixtures. Low concentration samples at 1 ppt levels showed significant signal variation due to their poor S/N ratio. Their S/N ratio can be improved by decreasing scan range from 0-260 to 70-80 for As related deconvolution. Current version of MassWorks can perform three components mixture analysis. In a future release, multiple components, virtually unlimited components can be performed with the spectral deconvulotion.
机译:对于用作标准,对称和数学良好定义的峰值进行的峰值形状校准,可以获得与[Cl〜( - )]一样掺入的混合物的所有ICP-MS光谱,并允许准确的光谱折叠和定量混合物。 1 ppt水平下的低浓度样品显示出由于其差的S / N比而显着的信号变化。通过将扫描范围从0-260〜70-80减小,可以提高它们的S / N比,以便与相关的解卷积。当前版本的批量可以执行三种组分混合分析。在未来的释放中,可以使用光谱折叠ulotion执行多个组件,几乎无限的组件。

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