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Plasmachemical Processes in Plasma-Assisted Combustion

机译:等离子体辅助燃烧中的性质气相过程

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We performed measurements of the gas flows (air and propane-air) temperatures in the barrier discharge. It was found that gas heating in a propane-air mixture is stronger than in the pure air. Basing on the results of numerical modelling we can conclude that additional heating in propane-air mixtures occurs due to radicals production in the discharge, and the direct thermal heating by the discharge is insufficient to promote a combustion. The main reasons for the temperature growth are additional energy release in chain reactions (this effect is important at high temperatures near the temperature of self-ignition) and the difference in mechanisms of O atoms recombination in air and propane-air: recombination in air proceeds via O-O and O-O2 collisions, while in propane-containing mixtures the recombination goes with OH radical formation -this process is much more faster. To prove the mechanism suggested above about the radical's role in the flame control by the barrier discharge we performed measurements of OH radical in the flame using LIF technique in time-resolved regime with an accuracy about 10/Lts. The results have showed that formation of OH radicals near the burner nozzle under the discharge action is similar to that one for OH(A). OH maximum corresponds to 1 fxs, this result coincide with calculations for OH dynamics which were performed using GRI-Mech 2.1.
机译:我们进行在阻挡放电气体流(空气和丙烷气)的温度的测量。据发现在丙烷 - 空气混合物的气体加热比在纯空气更强。基础上数值模拟的结果,我们可以得出结论,在丙烷 - 空气混合物另外加热的发生是由于自由基产生的放电,及由排出的直接加热是不足以促进燃烧。用于温度增长的主要原因是在链反应中额外的能量释放(这种效果是在自点火的温度附近高温重要)并在空气和丙烷 - 空气O原子重组机制的差异:在空气中进行的重组通过OO和O-O2碰撞,而在含丙烷的混合物的重组去与OH自由基的形成 - 这个过程是更快。为了证明以上建议关于在火焰中控制自由基的作用由我们进行使用LIF技术在时间分辨制度约10 /廖运华精度火焰自由基OH测量的阻挡层放电的机制。的结果已表明,在形成放电作用下在燃烧器喷嘴附近的OH自由基的类似于一个用于OH(A)。 OH最大对应于1个FXS,与计算所涉及使用GRI-机甲2.1执行OH动力学这一结果一致。

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