首页> 外文会议>International Conference on Advanced Ceramics and Composites >EFFECT OF RARE-EARTH DOPING ON THERMOELECTRIC PROPERTIES OF POROUS SiC SYNTHESIZED BY SILICON CARBONIZATION TECHNIQUE
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EFFECT OF RARE-EARTH DOPING ON THERMOELECTRIC PROPERTIES OF POROUS SiC SYNTHESIZED BY SILICON CARBONIZATION TECHNIQUE

机译:稀土掺杂对硅碳化技术合成多孔SiC热电性能的影响

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By means of the silicon carbonization technique using the graphite powder containing DV2O3 or Gd2O3, porous SiC in which Dy or Gd were finely dispersed, was successfully synthesized. The magnetic impurity densities estimated from the analysis of the magnetic properties of the Dy/Gd doped samples. There is little difference between the effective carrier densities and the magnetic impurity densities for the Gd doped samples. In contrast, for the Dy doped samples, the effective carrier densities were much larger than the magnetic impurity densities. These results indicated that Dy might be mainly doped near the surface of the SiC wafer. Hence the effective carrier densities of the Dy doped samples in the near surface region were considered to significantly increase in contrast to the ND samples. As a result, the power factors of the Dy doped samples were much improved to exhibit the highest value of 5.8 X 10~(-5) W/mK~2 at 897 K.
机译:通过使用含有DV2O3或GD2O3的石墨粉末的硅碳化技术,成功地合成了DY或GD的多孔SiC,被精细地合成。从DY / GD掺杂样品的磁性分析估计的磁性杂质密度。在GD掺杂样品的有效载体密度和磁杂质密度之间几乎没有差异。相反,对于掺杂的样品,有效的载体密度远大于磁杂质密度。这些结果表明,Dy可能主要掺杂在SiC晶片的表面附近。因此,与Nd样品相比,认为近表面区域中的Dy掺杂样品的有效载体密度明显增加。结果,Dy掺杂样品的功率因子大大改善,以在897K下表现出最高值为5.8×10〜(-5)W / MK〜2的值。

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