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EFFECT OF RARE-EARTH DOPING ON THERMOELECTRIC PROPERTIES OF POROUS SiC SYNTHESIZED BY SILICON CARBONIZATION TECHNIQUE

机译:稀土掺杂对硅碳化技术合成多孔SiC热电性能的影响

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By means of the silicon carbonization technique using the graphite powder containing Dy_2O_3 or Gd_2O_3, porous SiC in which Dy or Gd were finely dispersed, was successfully synthesized. The magnetic impurity densities estimated from the analysis of the magnetic properties of the Dy/Gd doped samples. There is little difference between the effective carrier densities and the magnetic impurity densities for the Gd doped samples. In contrast, for the Dy doped samples, the effective carrier densities were much larger than the magnetic impurity densities. These results indicated that Dy might be mainly doped near the surface of the SiC wafer. Hence the effective carrier densities of the Dy doped samples in the near surface region were considered to significantly increase in contrast to the ND samples. As a result, the power factors of the Dy doped samples were much improved to exhibit the highest value of 5.8 × 10~(-5) W/mK~2 at 897 K.
机译:通过使用含有Dy_2O_3或Gd_2O_3的石墨粉的硅碳化技术,成功地合成了其中Dy或Gd细分散的多孔SiC。磁性杂质密度是通过对Dy / Gd掺杂样品的磁性进行分析而得出的。 Gd掺杂样品的有效载流子密度和磁杂质密度之间几乎没有差异。相反,对于掺Dy的样品,有效载流子密度比磁性杂质密度大得多。这些结果表明,Dy可能主要掺杂在SiC晶片的表面附近。因此,与ND样品相比,认为在近表面区域中Dy掺杂样品的有效载流子密度显着增加。结果,Dy掺杂样品的功率因数大大提高,在897 K时呈现出5.8×10〜(-5)W / mK〜2的最大值。

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