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Lead-Free Solders and Isotropically Conductive Adhesives in Assembling of Silicon Solar Cells - Preliminary Results

机译:硅太阳能电池组装的无铅焊料和各向同性导电粘合剂 - 初步结果

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Most often the electrical interconnection of crystalline silicon solar cells within a photovoltaic module is made by soldering of tin-lead coated ribbons to the screen-printed busbar. During nearest years the lead-tin solders, most often used for this purpose, should be replaced by alternative interconnection materials - Pb-free solders or electrically conductive adhesives. This paper presents the electrical properties and long-term stability of joints between conductive tracks, screen-printed on alumina or on silicon, and proper flat ribbon in dependence of joint material. Joints were made from typical tin-lead solder (reference joint), lead-free solder or isotropically conductive adhesives. It was proved that tested lead-free solder could be applied for assembling of silicon solar cells even with typical tin-lead coated Cu ribbon. The adhesive joints are not so stable in this configuration. Probably this is connected with oxidation or galvanic corrosion of base metal during ageing at elevated temperature and humidity. But promising results appeared for silver-plated ribbon.
机译:最常经常通过将锡引线涂覆的丝带焊接到丝网印刷的汇流条来制造光伏模块内的晶体硅太阳能电池的电互连。在最近的岁月中,最常用于此目的的铅锡焊料应由替代互连材料 - 无铅焊料或导电粘合剂代替。本文介绍了导电轨道之间的接头的电性能和长期稳定性,在氧化铝或硅上印刷的丝网印刷,以及相当于接头材料的适当平坦的带。关节由典型的锡铅焊料(参考接头),无铅焊料或各向同性导电粘合剂制成。事实证明,即使用典型的锡铅涂覆的Cu带,可以应用测试的无铅焊料用于组装硅太阳能电池。在这种配置中,粘合剂不太稳定。可能这在升高的温度和湿度下老化期间,这与基础金属的氧化或电流腐蚀相连。但镀银带出现了有希望的结果。

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